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201.
Certain factors influencing the incorporation, transport and release of fatty acids by clay minerals, calcite and marine sediments have been investigated.Salinity was found to be an important factor. The adsorption of heptadecanoic acid by bentonite clay at 4%. was nearly triple that at 0%.. However, from 4%. to 35%., only a minor adsorption increase occurred. This behavior is believed to be related to flocculation of the clay at the lower salinity range. The pH over the range of 6.0–8.5 has a small influence on fatty acid-clay association, depressing it somewhat as the basicity increases.When the temperature of the fatty acid solution was increased from 0°C to 50°C, a decrease in adsorption on to clay was found. This effect may be due to increased water solubility of the acid at higher temperatures, since solubility is very important in controlling the degree of fatty acid-mineral interaction. Furthermore, apparent solubilization of fatty acids by indigenous dissolved organic matter in sea water reduces adsorption on to clay minerals.Based upon the heat of adsorption of ?14.6 kcal/mole, fatty acids are physically bound to clay minerals by weak van der Waals forces and hydrogen bonds.Bentonite and kaolinite were found to be the most adsorptive minerals investigated, followed in order by illite, montmorillonite and calcite. Sediments from Narragansett Bay were found to lie between illite and montmorillonite in adsorptive capacity after indigenous sediment organic matter had been removed. Sediment organic matter reduced fatty acid uptake by a factor of 1.6.  相似文献   
202.
The influence of solution complexation on the sorption of yttrium and the rare earth elements (YREEs) by amorphous ferric hydroxide was investigated at 25 °C over a range of pH (4.0-7.1) and carbonate concentrations . Distribution coefficients, defined as , where [MSi]T is the total concentration of sorbed YREE, MT is the total YREE concentration in solution, and [Si] is the concentration of amorphous ferric hydroxide, initially increased in magnitude with increasing carbonate concentration, and then decreased. The initial increase of is due to sorption of YREE carbonate complexes , in addition to sorption of free YREE ions (M3+). The subsequent decrease of , which is more extensive for the heavy REEs, is due to the increasing intensity of YREE solution complexation by carbonate ions. The competition for YREEs between solution complexation and surface complexation was modeled via the equation:
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204.
We present the first triangulation measurements of electric fields with the electron drift instrument (EDI) on Equator-S. We show results from five high-data-rate passes of the satellite through the near-midnight equatorial region, at geocentric distances of approximately 5–6 RE, during geomagnetically quiet conditions. In a co-rotating frame of reference, the measured electric fields have magnitudes of a few tenths of mV/m, with the E × B drift generally directed sunward but with large variations. Temporal variations of the electric field on time scales of several seconds to minutes are large compared to the average magnitude. Comparisons of the “DC” baseline of the EDI-measured electric fields with the mapped Weimer ionospheric model and the Rowland and Wygant CRRES measurements yield reasonable agreement.  相似文献   
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206.
Chirp sub-bottom profilers produce high-resolution images of the near-surface. An attribute of the sea-bed reflection in chirp data are fluctuations in polarity between adjacent traces. Two models are proposed and presented to explain this: the first incorporates changes in an acoustic impedance gradient at the sea bed; the second uses changes in the thickness of the uppermost sediment layer. Mixing of adjacent traces produces a consistent polarity for the sea-bed reflector. Reflection coefficients are calculated, using amplitude information derived from single-traces, and polarity information from trace mixing, with application to a marine archaeological case study. The reflection coefficient calculated for the top of a buried 18th century wooden wreck is -0.26.  相似文献   
207.
A Predictive Model for Frequently Viewed Tiles in a Web Map   总被引:1,自引:0,他引:1  
Distributing pre‐generated image tiles from a server‐side cache is a fast and popular way of serving maps on the Web. However, these caches can grow unmanageably large for maps covering many scales over a broad extent. This research presents a model for determining high‐priority geographic areas for tile caching. The model considers variables found in previous research to be of interest to Web map users, such as populated places, major roads, coastlines, and tourist attractions. The proportion of area, disk space, and time saved when creating a partial cache (consisting only of high‐interest areas) and a cache of the entire map extent are compared to establish that marked savings are possible. Several applications of the model beyond tile caching are briefly discussed.  相似文献   
208.
Invigorating hydrological research through journal publications   总被引:1,自引:1,他引:0  
Editors of several journals in the field of hydrology met during the General Assembly of the European Geosciences Union—EGU in Vienna in April 2017. This event was a follow-up of similar meetings held in 2013 and 2015. These meetings enable the group of editors to review the current status of the journals and the publication process, and to share thoughts on future strategies. Journals were represented at the 2017 meeting by their editors, as shown in the list of authors. The main points on invigorating hydrological research through journal publications are communicated in this joint editorial published in the above journals.  相似文献   
209.
Rainfall products can contain significantly different spatiotemporal estimates, depending on their underlying data and final constructed resolution. Commonly used products, such as rain gauges, rain gauge networks, and weather radar, differ in their information content regarding intensities, spatial variability, and natural climatic variability, therefore producing different estimates. Landscape evolution models (LEMs) simulate the geomorphic changes in landscapes, and current models can simulate timeframes from event level to millions of years and some use rainfall inputs to drive them. However, the impact of different rainfall products on LEM outputs has never been considered. This study uses the STREAP rainfall generator, calibrated using commonly used rainfall observation products, to produce longer rainfall records than the observations to drive the CAESAR-Lisflood LEM to examine how differences in rainfall products affect simulated landscapes. The results show that the simulation of changes to basin geomorphology is sensitive to the differences between rainfall products, with these differences expressed linearly in discharges but non-linearly in sediment yields. Furthermore, when applied over a 1500-year period, large differences in the simulated long profiles were observed, with the simulations producing greater sediment yields showing erosion extending further downstream. This suggests that the choice of rainfall product to drive LEMs has a large impact on the final simulated landscapes. The combination of rainfall generator model and LEMs represents a potentially powerful method for assessing the impacts of rainfall product differences on landscapes and their short- and long-term evolution. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd  相似文献   
210.
Wood additions to streams can slow water velocities and provide depositional areas for bacteria and fine particles (e.g., particulate organic carbon and nutrients sorbed to fine sediment), therefore increasing solute and particle residence times. Thus, wood additions are thought to create biogeochemical hotspots in streams. Added wood is expected to enhance in-stream heterogeneity, result in more complex flow paths, increase natural retention of fine particles and alter the geomorphic characteristics of the stream reach. Our aim was to directly measure the impact of wood additions on fine particle transport and retention processes. We conducted conservative solute and fluorescent fine particle tracer injection studies in a small agricultural stream in the Whatawhata catchment, North Island of New Zealand in two reaches—a control reach and a reach restored 1-year earlier by means of wood additions. Fine particles were quantified in surface water to assess reach-scale (channel thalweg) and habitat-scale (near wood) transport and retention. Following the injection, habitat-scale measurements were taken in biofilms on cobbles and by stirring streambed sediment to measure fine particles available for resuspension. Tracer injection results showed that fine particle retention was greater in the restored compared to the control reach, with increased habitat-scale particle counts and reach-scale particle retention. Particle deposition was positively correlated with cobble biofilm biomass. We also found that the addition of wood enhanced hydraulic complexity and increased the retention of solute and fine particles near the wood, especially near a channel spanning log. Furthermore, particles were more easily remobilized from the control reach. The mean particle size remobilized after stirring the sediments was ~5 μm, a similar size to both fine particulate organic matter and many microorganisms. These results demonstrate that particles in this size range are dynamic and more likely to remobilize and transport further downstream during bed mobilization events.  相似文献   
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